ДЕЯКІ ПИТАННЯ РЕЧОВИНОГО АНАЛІЗУ
DOI:
https://doi.org/10.18524/2304-0947.2016.4(60).83661Ключові слова:
речовинний аналіз, функціональні матеріали, визначення хімічних форм компонентів, неруйнівні методи аналізу, оксиди, фториди, халькогенідиАнотація
На підставі даних численних монографій і оглядових статей розглянуто загальні принципи і особливості речовиного аналізу різних об'єктів, як одного з актуальних напрямків сучасної аналітичної хімії. Відзначено, що підвищення інтересу до речовиного аналізу в останні роки зумовлено переважно біомедичними і екологічними завданнями. Зроблено висновок про недостатню увагу до проблем визначення хімічних форм компонентів різних неорганічних функціональних матеріалів. Підкреслено те, що при вирішенні таких завдань необхідно збереження форм аналіту в процесах переведення зразків, що аналізують, у розчин. Оптимальним визнано поєднання процедури розчинення зразку матеріалу у присутності реагентів, що селективно і кількісно реагують з відповідною хімічною формою елемента, та неруйнівного методу детектування. У якості останнього рекомендовано спектроскопію дифузного відбиття.
Посилання
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Stoyanov A.O., Stoyanova I.V., Chivireva N.A., Antonovich V.P. Ispol’zovanie proizvodnoi spektrofotometrii dlya obnaruzheniya i opredeleniya tseriya(III) v prisutstvii tseriya (IV). Ukr. khim. zhurn., 2013, vol. 79, no 2, pp. 98-101. (in Russian)
Chivireva N.A., Stoyanova I.V., Zinchenko V.F., Magunov I.R., Antonovich V.P., Stoyanov A.O. Opredelenie khimicheskikh form komponentov v produktakh vzaimodeistviya sul’foftoridov lantanidov s oksidom magniya. Ukr. khim. zhurn., 2013, vol. 79, no 8, pp. 106-110. (in Russian)
Stoyanov A.O., Khomenko E.V., Efryushina N.P., Stoyanova I.V., Chivireva N.A., Antonovich V.P. Opredelenie raznovalentnykh form tseriya v nanorazmernom kal’tsievom gidroksiapatite. Metody i ob’ekty khim.analiza, 2014, vol. 9, no 2, pp. 83-87. (in Russian)
Stoyanova I.V., Stoyanov A.O., Chivireva N.A., Zinchenko V.F., Timukhin E.V., Antonovich V.P. Identifikatsiya valentnikh form tseriya vo ftoridnikh materialakh metodom spektroskopii diffuznogo otrazheniya. Metody i ob’ekty khim. analiza, 2014, vol. 9, no 3, pp. 105-108. (in Russian)
Stoianov O.O., Ivanov V.K., Shcherbakov A.B., Stoyanova I.V., Chivireva N.A., Antonovich V.P. Determination of cerium(III) and cerium(IV) in nanodisperse ceria by chemical methods. Russ. J. Inorg. Chem., 2014, vol. 59, no 2, pp. 15-23. http://dx.doi.org/10.1134/s0036023614020181
Chivireva N.A., Stoyanova I.V., Zinchenko V.F., Stoyanov A.O., Magunov I.R., Mazur O.S., Antonovich V.P. Vybor parametrov spektrov diffuznogo otrazheniya dlya identifikatsii kislorodsoderzhashchikh primesei i stepeni vzaimodeistviya v sistemakh ZnS(ZnO)-Dy2S3. Metody i ob”ek-ty khim.analiza, 2015, vol. 10, no 1, pp. 11-17. (in Russian)
Stoyanova I.V., Chivireva N.A., Eremin O.G., Zinchenko V.F., Antonovich V.P. Otsenka soderzhaniya oksidnykh primesei vo ftoride svintsa(II) metodom spektroskopii diffuznogo otrazheniya. Ukr. khim. zhurn., 2016, vol. 82, no 1, pp. 6-10. (in Russian)
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