КАТІОННІ КООРДИНАЦІЙНІ СПОЛУКИ [Ln(Pip)2(Ph3PO)3]B(Ph)4 НА ОСНОВІ 2,2,2-ТРИХЛОРО-N- (ДИПІПЕРИДИНФОСФОРИЛ)АЦЕТАМІДУ

O. О. Litsis, Т. Yu Sliva, S. V. Shishkina, V. M. Аmirkhanov

Анотація


Синтезовано нові координаціні сполуки з лігандом карбациламідофосфатного (КАФ) типу 2,2,2-трихлоро-N-(дипіперидинфосфорил)ацетамідом (НРір) складу [Ln(Pip)2(Ph3PO)3]B(Ph)4·2H2O (де Ln = La, Nd, Еu, Lu), їх склад та будову підтверджено методами елементного аналізу та FT-IR спектроскопії. Структуру [Lа(Pip)2(Ph3PO)3]B(Ph)4·2H2O розшифровано методом повного РСтА. Для даного комплексу було визначено еквівалентну електропровідність та запропоновано схеми дисоціації комплексів у розведених неводних розчинах.

Ключові слова


карбациламідофосфат; хелатуючий О,О’-ліганд; лантаноїд; катіонний комплекс

Повний текст:

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Посилання


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Пристатейна бібліографія ГОСТ


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DOI: https://doi.org/10.18524/2304-0947.2016.2(58).74779

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