КООРДИНАЦІЙНІ СПОЛУКИ ПЕРЕХІДНИХ МЕТАЛІВ З БЕНЗГІДРАЗІДОМ

T. V. Koksharova, T. V. Mandzii, T. S. Skakun, Yu. A. Anisimov

Анотація


Дана характеристика бензгідразіду як ліганду в координаційних сполуках. Вказані потенційні області застосування бензгідразіду та його комплексів. Наведено загальну характеристику його здатності до комплексоутворення: донорні центри, таутомерні форми, теоретично можливі способи координації до металу. Розглянуто склад і будову бензгідразідних комплексів d-металів з різними аніонами. Для різних комплексоутворювачів охарактеризовані комплекси галогенідів, сульфатів, нітратів, тіоціанатів, перхлоратів, нітритів, ацетатів. Наведені приклади комплексів з кетонною та фенольною формами бензгідразіду. Розглянуто комплекси з сольватними молекулами води та метанолу. Для деяких сполук наведені загальні характеристики структур за даними РСА. Зазначено на особливості взаємодії з бензгідразідом солей міді(II) з різними аніонами. Наведено дані по комплексах ванадію, що включає бензгідразід з різними ступенями депротонування. Показано зміну способу зв’язування бензгідразіду зі ртуттю залежно від аніону. Наведені приклади біметалевих та змішанолігандних комплексів. Описано структуру комплексів [Co(НL)(Mal)(H2O)2]H2O (H2Mal – малонова кислота) і [Co(НL)3](OH)Cl(Н3Ssal)⋅H2O (Н3Ssal – 5-сульфосаліцилова кислота). Розглянуто аспекти біологічної активності деяких комплексів: бактерицидна, фунгіцидна, цитотоксична.


Ключові слова


координаційні сполуки; перехідні метали; бензгідразід

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Посилання


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Пристатейна бібліографія ГОСТ


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DOI: https://doi.org/10.18524/2304-0947.2017.1(61).94714

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