МОЛЕКУЛЯРНІ КОМПЛЕКСИ ОКСИДУ СІРКИ(IV) З N,O-ВМІСНИМИ ОРГАНІЧНИМИ ОСНОВАМИ (ОГЛЯД)

Автор(и)

  • R. E. Khoma Одеський національний університет імені І. І. Мечникова; Фізико-хімічний інститут захисту навколишнього середовища і людини, Ukraine
  • A. A. Ennan Фізико-хімічний інститут захисту навколишнього середовища і людини, Ukraine

DOI:

https://doi.org/10.18524/2304-0947.2016.3(59).79510

Ключові слова:

оксид сірки (IV), N, O-вмісні органічні основи, комплекси з переносом заряду, ван-дер-ваальсові комплекси

Анотація

Систематизовано та узагальнено літературні дані щодо синтезу, стехіометрії, будови  та відносної стійкості молекулярних комплексів оксиду сірки (IV) з N,O-вмісними органічними основами. Особливу увагу приділено механізмам утворення комплексів з переносом заряду, в яких реалізується S←N и S←O зв'язування, а також ван-дер-ваальсових комплексів. Відзначено кореляції між електронними, спектральними параметрами, будовою, відносною стійкістю і іншими характеристиками утворених сполук.

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2016-10-11

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Khoma, R. E., & Ennan, A. A. (2016). МОЛЕКУЛЯРНІ КОМПЛЕКСИ ОКСИДУ СІРКИ(IV) З N,O-ВМІСНИМИ ОРГАНІЧНИМИ ОСНОВАМИ (ОГЛЯД). Вісник Одеського національного університету. Хімія, 21(3(59), 6–31. https://doi.org/10.18524/2304-0947.2016.3(59).79510

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