МОЛЕКУЛЯРНІ КОМПЛЕКСИ ОКСИДУ СІРКИ(IV) З N,O-ВМІСНИМИ ОРГАНІЧНИМИ ОСНОВАМИ (ОГЛЯД)

R. E. Khoma, A. A. Ennan

Анотація


Систематизовано та узагальнено літературні дані щодо синтезу, стехіометрії, будови  та відносної стійкості молекулярних комплексів оксиду сірки (IV) з N,O-вмісними органічними основами. Особливу увагу приділено механізмам утворення комплексів з переносом заряду, в яких реалізується S←N и S←O зв'язування, а також ван-дер-ваальсових комплексів. Відзначено кореляції між електронними, спектральними параметрами, будовою, відносною стійкістю і іншими характеристиками утворених сполук.

Ключові слова


оксид сірки (IV); N,O-вмісні органічні основи; комплекси з переносом заряду; ван-дер-ваальсові комплекси

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DOI: https://doi.org/10.18524/2304-0947.2016.3(59).79510

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