DOI: https://doi.org/10.18524/2304-0947.2019.3(71).177725

СПРЯМОВАНИЙ СИНТЕЗ РІЗНОЛІГАНДНО- ГЕТЕРОМЕТАЛІЧНИХ КСИЛАРАТОГЕРМАНАТІВ Со(II) З 1,10-ФЕНАНТРОЛІНОМ ТА 2,2’-БІПІРИДИНОМ

E. A. Chebanenko, I. I. Seifullina, E. E. Martsinko

Анотація


Вперше синтезовано та досліджено методами елементного аналізу, термогравіметрії, ІЧ-спектроскопії різнолігандно-гетерометалічні ксиларатогерманати кобальту(II) з 1,10-фенантроліном (2,2’-біпіридином). На основі сукупності результатів фізичних та хімічних методів дослідження встановлено склад та будову отриманих сполук. Запропонована схема їх будови.

Ключові слова


германій; кобальт; ксиларова кислота; 1,10-фенантролін; 2,2’-біпіридин; координаційні сполуки

Повний текст:

PDF

Посилання


Kiselev Yu. M. Chemistry of coordination compounds. Moscow, Integral-Press, 2008, 728 p. (in Russian)

Lu P., Yao S., Cai J., Yang P. H. Synthesis and synergetic anti-tumor activity evaluation of dihydroartemisininorganogermanium(IV)compound. Bioorg. Med. Chem. Lett., 2014, vol. 24, no 22, pp. 5294–5297. https://doi.org/10.1016/j.bmcl.2014.09.048.

Nakamura T., Takeda T., Tokuji Y. The oral intake of organic germanium, Ge-132, elevates α-tocopherol levels in the plas-ma and modulates hepatic gene expression profiles to promote immune activation in mice. Int. J. Vitam. Nutr. Res., 2014, vol. 84, no 3–4, pp. 183–95. https://doi.org/10.1024/0300-9831/a000205.

Carballoa R., Coveloa B., Va´zquez-Lo´peza E.-M. Mixed-Ligand Complexes of Zinc(II) with α-Hydroxycarboxylates and Aromatic N-N Donor Ligands: Synthesis, Crystal Structures and Effect of Weak Interactions on their Crystal Packing. Z. Anorg. Allg. Chem., 2005, vol. 631, pp. 785-792. https://doi.org/10.1002/zaac.200400444.

Balbo S., Carballo R., Castiñeiras A. Mononuclear, dinuclear and hydroxo-bridged tetranuclear complexes from reactions of CuII ions, mandelic acid and diimine ligands. Polyhedron., 2008, vol. 27, pp. 2921-2930. https://doi.org/10.1021/ja0009121.

Xin-Wen Z., Juan-Juan D., Shu-Zhang X. Solid and solution study of tetranuclear zinc citrates with N-donor chelates. J. Coord. Chem., 2014, vol. 67, no 14, pp. 2470-2478. https://doi.org/10.1080/00958972.2014.944174.

Cai J.-H., Jiang Y.-M., Weng S. 2-Aminoethanesulfonato-k2N,O)bis(1,10-phenanthroline- k2N,N’)cobalt(II) perchlorate monohydrate. Acta Cryst. E., 2006, vol. 62, pp. m3059-m3061. http://dx.doi.org/10.1107/S1600536806041584.

Vreshch O. V., Nesterova O. V., Kokozay V. N., Dyakonenko V. V. Sodium Nitroprusside as a Source of Metalloligand in Direct Synthesis of Cu/Fe Complexes. Z. Anorg. Allg. Chem., 2009, vol. 635, pp. 2316-2323. http://dx.doi.org/10.1002/zaac.200900017.

Hua A.-Y., Chen X., Chen Y.-Y., Zhou H. Time-of-diffusion dependent structural diversity in the MII-phentetracyanometalates (M = Zn, Mn) supramolecular system. J. Mol. Struct., 2013, vol. 1037, pp. 301-304. http://dx.doi.org/10.1016/j.molstruc.2013.01.010.

Pruchnik F. P., Urszula D., Kochel A. Structure and properties of the dinuclear complex [Co2(μ-OAc)2(OAc)2(μ-H2O)(phen)2]. Polyhedron, 2006, vol. 25, pp. 3647–3652. http://dx.doi.org/10.1016/j.poly.2006.07.023.

Rusanov J. A., Kozachuk O. V., Dyakonenko V. V. Bis[chloridobis(1,10-phenanthroline)copper(II)] pentacyanido-nitrosoferrate(II) dimethylformamide monosolvate. Acta Cryst. E., 2013, vol. 69, pp. m391-m392. http://dx.doi.org/10.1107/S1600536813015547.

Chen J., Chai W., L. Song, Yang Y. A double salt of iodobismuthate: cis-aquaiodidobis(1,10-phenanthroline)-cobalt(II) tris(1,10-phenanthroline)-cobalt(II) trans-hexa-l2-iodido-hexaiodidotribismuthate(III). Acta Cryst.E., 2011, vol. 67, pp. m1284–m1285. http://dx.doi.org/10.1107/S1600536811033460.

Xu W. Catena-Poly[[[aqua(formato-kO)(1,10-phenanthroline-k2N,N’)manganese(II)]-μ-formato-k2O:O’] monohydrate] Acta Cryst. E., 2011, vol. 67, pp. m893. http://dx.doi.org/ 10.1107/S1600536811020575.

Li-Min L., Yu-Feng L., Liu L., Zeng-Hui Z. Tris(1,10-phenanthroline)cobalt(II) bis(trichloroacetate). Acta Cryst. E., 2011, vol. 67, pp. m973. http://dx.doi.org/ 10.1107/S160053681102410X.

Zi-Lu C., Yu-Zhen Z., Fu-Pei L. A novel nickel(II) coordination polymer incorporating 1,4-phenylene-diacetic acid and 1,10-phenanthroline . Acta Cryst. C., 2006, vol. 62, pp. m48-m50. http://dx.doi.org/ 10.1107/ S0108270105042575.

Uvarova M. A.,. Kushan E. V, Nefedov S. E. Structure of Reaction Products of Hydrous and Anhydrous Zinc Acetates with 1,10-Phenanthroline. Russ. J. Inorg. Chem., 2012, vol. 57, no 4, pp. 515-524. https://doi.org/10.1134/S0036023612040249.

Timothy J. P., Rujiwatra A., Chimupala Y. Ni(1,10-phenanthroline)2(H2O)2](NO3)2: A Simple Coordination Complex with a Remarkably Complicated Structure that Simplifies on Heating. Russ. Cryst., 2011, vol. 1, no 3. pp. 178-194. http://dx.doi.org/10.3390/cryst1030178.

McCann M., Geraghty M., Devereux M.,O’Shea D., Mason J., O’Sullivan L. Insights into the mode of action of the anti-Candida activity of 1,10-phenanthroline and its metal chelates. Met.-Based Drugs., 2000, vol. 7, no 4, pp. 185-193. http://dx.doi.org/10.1155/MBD.2000.185.

Alyautdin R.N., Preferansky N.G., Preferanskaya N.G. Pharmacology. Moscow, «GEOTAR-Media», 2010, 42 p. (in Russian)

Seifullina I., Martsinko E., Chebanenko E., Afanasenko E., Dyakonenko V., Shishkina S. Supramolecular organization and structure of Cu(II) and Ni(II), 2,2-bipyridine cations with tartratogermanate anions. Polyhedron, 2019, vol. 169, pp. 261-265. https://doi.org/10.1016/j.poly.2019.04.061

Seifullina I. I., Martsinko E. E., Chebanenko E. A., Afanasenko E. V., Shishkina S. V., D’yakonenko V. V. Complex Formation Products in the GeO2–Tartaric Acid–CuCl2–1,10-Phenanthroline System: Syntheses and Structures. Russ. J. Coord. Chem., 2019, vol. 45, no 7, pp. 496-504. https://doi.org/10.1134/S0132344X19060069.

Martsinko E., Seifullina I., Chebanenko E., Pirozhok O., Dyakonenko V., Shishkina S. Synthesis and crystal structure of bis(citrato)germanate and stannate with tris(phenanthroline)nickel(II) cation. Chemistry Journal of Moldova, 2018, vol. 13, no 2, pp. 52-57. http://dx.doi.org/10.19261/cjm.2018.513.

Martsinko E. E., Chebanenko E. A., Pirozhok O. V., Seyfullina I. I., D’yakonenko V. V., Shishkina S. V. Modification of bis(citrate)germanates with hexaquacations of cobalt (II) and manganese (II) 1,10-phenatrolin. Voprosy Khimii i Khimicheskoi Tekhnologi., 2018, no 6, pp. 1472-1477. http://dx.doi.org/10.32434/0321-4095-2018-121-6-49-55.

Seifullina I. I., Martsinko E. E., Chebanenko E. A., Pirozhok O. V., Dyakonenko V. V., Shishkina S. V. Structure of bis(citrato)germinates with different types of cations: (Hphen)2[Ge(HCit)2•3H2O], [CuCl(phen)2]2[Ge(HCit)2•6H2O], where H4Cit is citric acid, phen is 1,10-phenanthroline. J. Struct. Chem., 2017, vol. 58, no 3, pp. 577-583. http://dx.doi.org/10.1134/S0022476617030143.

Seifullina I., Martsinko E., Chebanenko E., Afanasenko Е., Dyakonenko V., Shishkina S. Synthesis, structure and investigation of germanium(IV) and copper(II) complexes with malic acid and 1,10-phenanthroline. Chem. J. Moldova, 2017, vol. 12, no 2, pp. 52-57. http://dx.doi.org/10.19261/cjm.2016.369.

Seifullina I. I., Martsinko E. E., Chebanenko E. A., Pirozhok O. V., Dyakonenko V. V., Shishkina S. V. Synthesis, thermal stability, and structure of bis(citrato)germanates: [Co(Phen)3][Ge(HCit)2]•2H2O, [Fe(Phen)3][Ge(HCit)2]•4H2O (H4Cit = citric acid, Phen = 1,10-phenanthroline). Russ. J. Coord. Chem., 2017, vol. 43, no 8, pp. 476-481. https://doi.org/10.1134/S1070328417080061.

Chebanenko E. A., Seifullina I. I., Martsinko E. E., D’yakonenko V. V., Shishkina S. V. Synthesis and Structure of Frame Xylaratogermanate Salts with Protonated Phenanthroline and Its Complexes with Fe(III) and Ni(II) as Cations. Russ. J. Inorg. Chem., 2019, vol. 64, no 9, pp. 951-956. http://dx.doi.org/10.1134/S0036023619090043.

Chebanenko E. A., Martsinko E. E, Seifullina I. I., D’yakonenko V. V., Shishkina S. V. Structural features and properties of heteronuclear germanium(IV) and some 3d metal complexes with xylaric acid and 2,2′-bipyridine. J. Struct. Chem., 2019, vol. 59, no 6, pp. 1462-1468. http://dx.doi.org/10.1134/S0022476618060318.

Allen F.H. The Cambridge Structural Database: a quarter of a million crystal structures and rising. Acta Crystallogr. B., 2002, vol. 58В, no 3, pp.380-388. https://doi.org/10.1107/S0108768102003890.

Seifullina I.I., Martsinko E.E. Koordinatsionnyie soedineniya germaniya(IV) s anionami limonnoy, vinnoy I ksilarovoy kislot. Odessa, ONU, 2015, 148 p. (in Russian)

Gar T. K., Minaeva N. A., Mironov V. F., Chumaevsky N. A. Infrared absorption spectra of germanium compounds. Moscow, Nauka, 1977, 464 p.

Bellamy L.J. The Infra-red spectra of complex molecules. London, Chapman and Hall, 1975, 433 p. http:// dx.doi.org/ 10.1007/978-94-011-6017-9.

Tarasevich B.N. IK spektryi osnovnyih klassov organicheskih soedineniy. Moscow, MGU, 2012, 54 р. (in Russian)

Medina G., Gasque L., BerneAs S. Aqua [μ‐lactate‐O,O′](1,10‐phenanthroline‐κ2N,N′)copper(II) nitrate. Acta Cryst., 2002, vol. 58, pp. m765 – m767. https://doi.org/10.1107/S1600536802021591.


Пристатейна бібліографія ГОСТ


1. Киселев Ю. М. Химия координационных соединений. – М.: Интеграл-Пресс, 2008. – 728 с.

2. Lu P., Yao S., Cai J., Yang P. H. Synthesis and synergetic anti-tumor activity evaluation of dihydroartemisininorganogermanium( IV)compound // Bioorg. Med. Chem. Lett. – 2014. – Vol. 24, N 22. – P. 5294–5297. https://doi.org/10.1016/j.bmcl.2014.09.048.

3. Nakamura T., Takeda T., Tokuji Y. The oral intake of organic germanium, Ge-132, elevates α-tocopherol levels in the plas-ma and modulates hepatic gene expression profiles to promote immune activation in mice // Int. J. Vitam. Nutr. Res. – 2014. – Vol. 84, N 3–4. – P. 183–95. https://doi.org/10.1024/0300-9831/a000205.

4. Carballoa R., Coveloa B., Va´zquez-Lo´peza E.-M. Mixed-Ligand Complexes of Zinc(II) with α-Hydroxycarboxylates and Aromatic N-N Donor Ligands: Synthesis, Crystal Structures and Effect of Weak Interactions on their Crystal Packing // Z. Anorg. Allg. Chem. – 2005. – Vol. 631. – P. 785-792. https://doi.org/10.1002/zaac.200400444.

5. Balbo S., Carballo R., Castiñeiras A. Mononuclear, dinuclear and hydroxo-bridged tetranuclear complexes from reactions of CuII ions, mandelic acid and diimine ligands // Polyhedron. – 2008. – Vol. 27. – P. 2921-2930. https://doi.org/10.1021/ja0009121.

6. Xin-Wen Z., Juan-Juan D., Shu-Zhang X. Solid and solution study of tetranuclear zinc citrates with N-donor chelates // J. Coord. Chem. – 2014. – Vol. 67, N 14. – P. 2470-2478. https://doi.org/10.1080/00958972.2014.944174.

7. Cai J.-H., Jiang Y.-M., Weng S. 2-Aminoethanesulfonato-k2N,O)bis(1,10-phenanthroline- k2N,N’)cobalt(II) perchlorate monohydrate // Acta Cryst. E. – 2006. – Vol. 62. – P. m3059-m3061. http://dx.doi.org/10.1107/S1600536806041584.

8. Vreshch O. V., Nesterova O. V., Kokozay V. N., Dyakonenko V. V. Sodium Nitroprusside as a Source of Metalloligand in Direct Synthesis of Cu/Fe Complexes // Z. Anorg. Allg. Chem. – 2009. – Vol. 635. – P. 2316-2323. http://dx.doi.org/10.1002/zaac.200900017.

9. Hua A.-Y., Chen X., Chen Y.-Y., Zhou H. Time-of-diffusion dependent structural diversity in the MII-phentetracyanometalates (M = Zn, Mn) supramolecular system // J. Mol. Struct. – 2013. – Vol. 1037. – P. 301-304. http://dx.doi.org/10.1016/j.molstruc.2013.01.010.

10. Pruchnik F. P., Urszula D., Kochel A. Structure and properties of the dinuclear complex [Co2(μ-OAc)2(OAc)2(μ-H2O)(phen)2] // Polyhedron. – 2006. – Vol. 25. – P. 3647–3652. http://dx.doi.org/10.1016/j.poly.2006.07.023.

11. Rusanov J. A., Kozachuk O. V., Dyakonenko V. V. Bis[chloridobis(1,10-phenanthroline)copper(II)] pentacyanidonitrosoferrate(II) dimethylformamide monosolvate // Acta Cryst. E. – 2013. – Vol. 69. – P. m391-m392. http://dx.doi.org/ 10.1107/S1600536813015547.

12. Chen J., Chai W., L. Song, Yang Y. A double salt of iodobismuthate: cis-aquaiodidobis(1,10-phenanthroline)-cobalt(II) tris(1,10-phenanthroline)-cobalt(II) trans-hexa-l2-iodido-hexaiodidotribismuthate(III) // Acta Cryst.E. – 2011. – Vol. 67. – P. m1284–m1285. http://dx.doi.org/10.1107/S1600536811033460.

13. Xu W. Catena-Poly[[[aqua(formato-kO)(1,10-phenanthroline-k2N,N’)manganese(II)]-μ-formato-k2O:O’] monohydrate] // Acta Cryst. E. – 2011. – Vol. 67. – P. m893. http://dx.doi.org/ 10.1107/S1600536811020575.

14. Li-Min L., Yu-Feng L., Liu L., Zeng-Hui Z. Tris(1,10-phenanthroline)cobalt(II) bis(trichloroacetate) // Acta Cryst. E. – 2011. – Vol. 67. – P. m973. http://dx.doi.org/ 10.1107/S160053681102410X.

15. Zi-Lu C., Yu-Zhen Z., Fu-Pei L. A novel nickel(II) coordination polymer incorporating 1,4-phenylene-diacetic acid and 1,10-phenanthroline // Acta Cryst. C. – 2006. – Vol. 62. – P. m48-m50. http://dx.doi.org/10.1107/S0108270105042575.

16. Uvarova M. A.,. Kushan E. V, Nefedov S. E. Structure of Reaction Products of Hydrous and Anhydrous Zinc Acetates with 1,10-Phenanthroline // Russ. J. Inorg. Chem. – 2012. – Vol. 57, N 4. – P. 515-524. https://doi.org/10.1134/S0036023612040249.

17. Timothy J. P., Rujiwatra A., Chimupala Y. Ni(1,10-phenanthroline)2(H2O)2](NO3)2: A Simple Coordination Complex with a Remarkably Complicated Structure that Simplifies on Heating // Russ. Cryst. – 2011. – Vol. 1, N 3. – P. 178-194. http://dx.doi.org/10.3390/cryst1030178.

18. McCann M., Geraghty M., Devereux M.,O’Shea D., Mason J., O’Sullivan L. Insights into the mode of action of the anti-Candida activity of 1,10-phenanthroline and its metal chelates // Met.-Based Drugs. – 2000. – Vol. 7, N 4. – P. 185-193. http://dx.doi.org/10.1155/MBD.2000.185.

19. Аляутдин Р. Н., Преферанский Н. Г., Преферанская Н. Г Фармакология. – М.: «ГЭОТАР-Медия», 2010. –42 с.

20. Seifullina I., Martsinko E., Chebanenko E., Afanasenko E., Dyakonenko V., Shishkina S. Supramolecular organization and structure of Cu(II) and Ni(II), 2,2-bipyridine cations with tartratogermanate anions // Polyhedron. – 2019. – Vol. 169. – P. 261-265. https://doi.org/10.1016/j.poly.2019.04.061

21. Seifullina I. I., Martsinko E. E., Chebanenko E. A., Afanasenko E. V., Shishkina S. V., D’yakonenko V. V. Complex Formation Products in the GeO2–Tartaric Acid–CuCl2–1,10-Phenanthroline System: Syntheses and Structures // Russ. J. Coord. Chem. – 2019. – Vol. 45, N 7. – P. 496-504. https://doi.org/10.1134/S0132344X19060069.

22. Martsinko E., Seifullina I., Chebanenko E., Pirozhok O., Dyakonenko V., Shishkina S. Synthesis and crystal structure of bis(citrato)germanate and stannate with tris(phenanthroline)nickel(II) cation // Chemistry Journal of Moldova – 2018. – Vol. 13, N 2. – P. 52-57. http://dx.doi.org/10.19261/cjm.2018.513.

23. Марцинко Е.Э., Чебаненко Е.А., Пирожок О.В., Сейфуллина И.И., Дьяконенко В.В., Шишкина С.В. Модификация бис(цитрато)германатов с гексааквакатионами кобальта(II) и марганца(II) 1,10-фенатролином // Вопросы химии и хим. технологи. – 2018. – № 6. – С. 1472-1477. http://dx.doi.org/10.32434/0321-4095-2018-121-6-49-55.

24. Seifullina I. I., Martsinko E. E., Chebanenko E. A., Pirozhok O. V., Dyakonenko V. V., Shishkina S. V. Structure of bis(citrato)germinates with different types of cations: (Hphen)2[Ge(HCit)2•3H2O], [CuCl(phen)2]2[Ge(HCit)2•6H2O], where H4Cit is citric acid, phen is 1,10-phenanthroline // J. Struct. Chem. –2017. – Vol. 58, N 3. – P. 577-583. http://dx.doi.org/10.1134/S0022476617030143.

25. Seifullina I., Martsinko E., Chebanenko E., Afanasenko Е., Dyakonenko V., Shishkina S. Synthesis, structure and investigation of germanium(IV) and copper(II) complexes with malic acid and 1,10-phenanthroline // Chemistry Journal of Moldova. – 2017. – Vol. 12, N 2. – P. 52-57. http://dx.doi.org/10.19261/cjm.2016.369.

26. Seifullina I. I., Martsinko E. E., Chebanenko E. A., Pirozhok O. V., Dyakonenko V. V., Shishkina S. V. Synthesis, thermal stability, and structure of bis(citrato)germanates: [Co(Phen)3][Ge(HCit)2]•2H2O, [Fe(Phen)3][Ge(HCit)2]•4H2O (H4Cit = citric acid, Phen = 1,10-phenanthroline) // Russ. J. Coord. Chem. – 2017. – Vol. 43,N 8. – P. 476-481. https://doi.org/10.1134/S1070328417080061.

27. Chebanenko E. A., Seifullina I. I., Martsinko E. E., D’yakonenko V. V., Shishkina S. V. Synthesis and Structure of Frame Xylaratogermanate Salts with Protonated Phenanthroline and Its Complexes with Fe(III) and Ni(II) as Cations // Russ. J. Inorg. Chem. – 2019. – Vol. 64, N 9. – P. 951-956. http://dx.doi.org/10.1134/ S0036023619090043.

28. Chebanenko E. A., Martsinko E. E, Seifullina I. I., D’yakonenko V. V., Shishkina S. V. Structural features and properties of heteronuclear germanium(IV) and some 3d metal complexes with xylaric acid and 2,2′-bipyridine // J. Struct. Chem. – 2019. – Vol. 59, N 6. – P. 1462-1468. http://dx.doi.org/10.1134/S0022476618060318.

29. Allen F.H. The Cambridge Structural Database: a quarter of a million crystal structures and rising // Acta Crystallogr. B. – 2002. – Vol. 58В, N 3. – P.380-388. https://doi.org/10.1107/S0108768102003890.

30. Сейфуллина И.И., Марцинко Е.Э. Координационные соединения германия(IV) с анионами лимонной, винной и ксиларовой кислот. Одесса: ОНУ, 2015. – 148 с.

31. Гар Т. К., Минаева Н. А., Миронов В. Ф., Чумаевский Н. А. Инфракрасные спектры поглощения соединений германия. – М: Наука, 1977. – 464 c.

32. Bellamy L.J. The Infr-red spectra of complex molecules. London: Chapman and Hall, 1975. – 433 p. http://dx.doi.org/ 10.1007/978-94-011-6017-9.

33. Тарасевич Б.Н. ИК спектры основных классов органических соединений. – М: Изд. МГУ, 2012. – 54 с.

34. Medina G., Gasque L., BerneAs S. Aqua [μ‐lactate‐O,O′](1,10‐phenanthroline‐κ2N,N′)copper(II) nitrate // Acta Cryst. – 2002. – Vol. 58. – P. m765 – m767. https://doi.org/10.1107/S1600536802021591.





Creative Commons License
Ця робота ліцензована Creative Commons Attribution-ShareAlike 4.0 International License.