ТЕОРЕТИЧНІ ОСНОВИ РОЗРОБКИ НАНЕСЕНИХ МЕТАЛОКОМПЛЕКСНИХ КАТАЛІЗАТОРІВ

Автор(и)

  • T. L. Rakitskaya Одеський національний університет імені І. І. Мечникова, кафедра неорганічної хімії та хімічної екології, Україна

DOI:

https://doi.org/10.18524/2304-0947.2015.1(53).44542

Ключові слова:

нанесені металокомплексні каталізатори, редокс-реакції, фосфін, монооксид вуглецю, озон

Анотація

Узагальнено результати досліджень в галузі розробки нанесених на різні носії металокомплексних каталізаторів. Описано можливі механізми каталітичних редокс-реакцій за участю таких токсичних газоподібних речовин, як фосфін, монооксид вуглецю та озон. Особливу увагу приділено фізико-хімічному обґрунтуванню вибору найбільш придатних носіїв.

Посилання

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Rakitskaya T.L., Kiose T.A., Oleksenko L.P., Verbeckaja T.G., Zrjutina A.M., Kameneva A.V. Vlijanie vlagosoderzhanija

na aktivnost' zakreplennogo na kislotno-modificirovannom klinoptilolite Pd(II)-Cu(II)–katalizatora v reakcii nizkotemperaturnogo okislenija monooksida ugleroda [The water content influence on the activity of the acid-modified clinoptilolite anchored Pd(II)-Cu(II) catalyst in the reaction of low-temperature carbon monoxide oxidation]. Visn. Odes'k. nac. un-tu. Himija, 2011, vol. 16, no. 4, pp. 5-11 (in Russian).

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Rakitskaya T.L., Granatyuk I.V., Balavoine G.G.A., Geletii Yu.V., Golub A.A., Raskola L.A. Features of transition metal sorption on silica gel and activity of catalysts formed thereby in ozone decomposition reaction. “Silica-98”: Int. Conf. Silica Sci. Technol.: Book Ext. Abstr., France, Mulhouse, 1998, pp. 653-656.

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Rakitskaya T.L., Bandurko A.Ju., Ennan A.A., Litvinskaja V.V. Kinetika nizkotemperaturnogo razlozhenija ozona uglerodnymi voloknistymi materialami [The kinetics of low-temperature ozone decomposition by carbon fibrous materials]. Kinetika i kataliz, 1994, vol. 35, no. 5, pp. 763-765 (in Russian).

Rakitskaya T.L., Vasil'eva E.K., Bandurko A.Ju., Paina V.Ja. Kinetika razlozhenija ozona aktivirovannymi ugljami [The kinetics of ozone decomposition by activated carbons]. Kinetika i kataliz, 1994, vol. 35, no. 1, pp. 103-105 (in Russian).

Rakitskaya T.L., Ennan A.A., Bandurko A.Ju. Uglerodnye voloknistye materialy dlja respiratora «Snezhok GPOzon » [Carbon fibrous materials for a “Snezhok GP-Ozon” respirator]. Avtomat. svarka, 1995, no. 7, pp. 62-64 (in Russian).

Rakitskaya T.L., Bandurko A.Ju., Boginskaja O.V. Nizkotemperaturnoe razlozhenie mikrokoncentracij ozona uglerodnymi voloknistymi materialami [The low-temperature ozone decomposition by carbon fibrous materials]. Zhurn. priklad. himii, 1996, vol. 69, no. 1, pp. 167‑169 (in Russian).

Rakitskaya T.L., Granatjuk I.V. Adsorbcionnye Co(II)-katalizatory nizkotemperaturnogo razlozhenija ozona [Adsorption Co(II) catalysts for low-temperature ozone decomposition]. Izv. vyssh. ucheb. zaved. Himija i him. tehnologija,, 1997, vol. 40, no. 1, pp. 14-18 (in Russian).

Rakitskaya T.L., Granatjuk I.V., Raskola L.A. Adsorbcionnye Men+-katalizatory razlozhenija ozona [Adsorption Men+ catalysts for low-temperature ozone decomposition]. Visn. Odes'k. nac. un-tu, 1998, no. 2, pp. 7-11 (in Russian).

Rakitskaya T.L., Raskola L.A., Paina V.Ja., Bandurko A.Ju. Geterogenezirovannyj Cu(II)-SiO2-katalizator razlozhenija ozona [A heterogenized Cu(II)-SiO2 catalyst for ozone decomposition]. Izv. vyssh. ucheb. zaved. Himija i him. tehnologija,, 1999, vol. 42, no. 1, pp. 46-49 (in Russian).

Rakitskaya T.L., Bandurko A.Yu., Ennan A.A., Paina V.Ya. Catalysts for sanitary air cleaning from ozone. Catalysis Today, 1999, vol. 53, no. 4, pp. 703-713.

Rakitskaya T.L., Ennan A.A., Granatyuk I.V., Bandurko A.Yu., Balavoine G.G.A. , Geletii Yu.V., Paina V.Ya. Kinetics and mechanism of low-temperature ozone decomposition by Co-ions adsorbed on silica. Catalysis Today, 1999, vol. 53, no. 4, pp. 715-723.

Rakitskaya T.L., Bandurko A.Yu., Ennan A.A., Paina V.Ya., Litvinskaya V.V. Low-temperature catalytic decomposition of ozone microconcentrations by carbon fibrous materials. Advances Environ. Research, 2000, vol. 3, no. 4, pp. 472-487.

Rakitskaya T.L., Golub A.A., Ennan A.A., Raskola L.A., Paina V.Ya., Bandurko A.Yu., Ped’ L.L.Schiff bases containing metal complexes anchored on aerosil as catalysts of low-temperature ozone decomposition. Stud. Surf. Sci. Catal., 2000, vol.130D, pp. 3879-3884.

Rakyts’ka T.L., Golub O.A., Raskola L.A., Bandurko O.Ju., Pidmazko A.S., Zujeva I.V., Ped’ L.L., Kudrenko V.A. Kompleksy vanadylu z immobilizovanym na aerosyli salicylal’iminom u reakcii’ nyz’kotemperaturnogo rozkladu ozonu [Vanadyl complexes with aerosil immobilized salicylaldimine in the reaction of low-temperature ozone decomposition]. Ukr. him. zhurn., 2001, vol. 67, no. 10, pp. 79-82 (in Ukrainian).

Rakitskaya T.L., Bandurko A.Yu., Ennan A.A., Paina V.Ya., Rakitskiy A.S. Carbon-fibrous-material-supported base catalysts of ozone decomposition. Microporous Mesoporous Mater., 2001, vol. 43, no. 2, pp. 153-160.

Rakitskaya T.L., Podmazko A.S. Nizkotemperaturnoe razlozhenie ozona nanesennym na SiO2 geksametilentetraminom [The low-temperature ozone decomposition with SiO2 supported hexamethylenetetramine]. Trudy 1 Mezhdunarodnoj nauchno-prakticheskoj konferenci «Zashhita okruzhajushhej sredy, zdorov'e, bezopasnost' v svarochnom proizvodstve»: [Proc. 1st Int. Conf. “Environment protection, health and safety in welding”].Ukraine. Odessa, 2002, pp. 401-404 (in Russian).

Rakitskaya T.L., Pidmazko A.S., Paskalova S.I. Nyz'kotemperaturnyj rozklad mikrokoncentracij ozonu nanesenym na sylikagel' geksametylentetraminom [The low-temperature decomposition of ozone microconcentrations with silica gel supported hexamethylenetetramine]. Visn. Odes'k. nac. un-tu. Himija, 2002, vol. 7, no. 5-6, pp. 90-97 (in Ukrainian).

Rakitskaya T.L., Raskola L.A., Bandurko A.Yu. Okysnennja ozonom nanesenogo na sylikagel' manganu(II) [The oxidation of silica gel supported manganese(II) with ozone]. Visn. Odes'k. nac. un-tu. Himija, 2002, vol. 7, no. 5-6, pp. 3-13 (in Ukrainian).

Rakitskaya T.L., Podmazko A.S., Shihaleeva G.N., Ennan A.A., Bandurko A.Yu., Lobanov V.V. Vzaimodejstvie nanesennogo na silikagel' geksametilentetramina s ozonom / [The interaction of silica gel supported hexamethylenetetramine with ozone]. Izv. vyssh. ucheb. zaved. Himija i him. tehnologija,, 2003, vol. 46, no. 2, pp. 135-138 (in Russian).

Rakitskaya T.L., Bandurko A.Yu., Sirovetnik O.V., Janjuk I.L. Issledovanie zashhitnyh svojstv ot mikrokoncentracij ozona kompleksov 3d-metallov s immobilizovannymi na ajerosile osnovanijami Shiffa [The study of protective properties of complexes of 3d metals with aerosil immobilized Schiff bases against ozone microconcentrations].Visn. Odes'k. nac. un-tu. Himija, 2003, vol. 8, no. 7-8, pp. 14-23 (in Russia).

Rakitskaya T.L., Podmazko A.S.. Nizkotemperaturnyj reagentnyj metod ochistki vozduha ot ozona [A lowtemperature reagent method for air purification from ozone]. Voprosy khimii i khimicheskoi technologii, 2003, no. 1, pp. 171-174 (in Russian).

Rakyts’ka T.L., Pidmazko A.S., Golub O.A., Bandurko O.Ju., Ped’ L.L., Kudrenko V.A., Radchenko Je.O. Kompleksy kuprumu(II) z immobilizovanymy na kremnezemi osnovamy Shyffa v reakcii’ rozkladu ozonu [Complexes of copper(II) with silica immobilized Schiff bases in the reaction of ozone decomposition]. Ukr. him. zhurn., 2004, vol. 70, no. 1-2, pp. 16-19 (in Ukrainian).

Rakitskaya T.L., Hitrich V.F., Raskola L.A., Makordej F.V., Sirovetnik O.V. Razlozhenie mikrokoncentracij ozona melkodispersnym MnO2-katalizatorom [The decomposition of ozone microconcentrations with a finedispersed MnO2 catalyst]. Visn. Odes'k. nac. un-tu. Himija, 2004, vol. 9, no. 6-7, pp. 117-124 (in Russian).

Rakitskaya T.L., Bandurko A.Yu., Truba A.S. Kinetika razlozhenija ozona kompleksami medi(ІІ) s immobilizovannymi na ajerosile 2-gidrokso-3-metoksibenzal'degidiminom [The kinetics of ozone decomposition with complexes of copper(II) with aerosil immobilized 2-hydroxo-3-methoxybenzaldehydeimine]. Visn. Odes'k. nac. un-tu. Himija, 2005, vol. 10, no. 2, pp. 170-179 (in Russian).

Rakitskaya T.L., Hitrich V.F., Raskola L.A., Chernovolova Z.V. Kinetika razlozhenija ozona melkodispersnym dioksidom marganca [The kinetics of ozone decomposition with fine-dispersed manganese dioxide]. Visn. Odes'k. nac. un-tu. Himija, 2005, vol. 10, no. 1, pp. 42-47 (in Russian).

Rakitskaya T.L., Truba A.S., Raskola L.A., Bandurko A.Ju., Golub A.A. Vlijanie stroenija adsorbirovannyh na poverhnost' SiO2 kompleksov medi(II) na ih kataliticheskuju aktivnost' v reakcii razlozhenija ozona [The influence of a structure of SiO2 surface adsorbed copper(II) complexes on their catalytic activity in the reaction of ozone decomposition]. Teoret. i jeksperim. himija, 2006, vol. 42, no. 1, pp. 55-60 (in Russian).

Golub A.A. Kompleksy 3d-metallov s immobilizovannymi na ajerosile 2-gidroksi-3-metoksibenzal'iminpropiilom i 4-gidroksi-3-metoksibenzal'iminpropiilom v reakcii razlozhenija ozona [Complexes of 3d metals with aerosol immobilized 2-hydroxy-3-methoxybenzaldiminepropyl and 4-hydroxy-3-methoxybenzaldiminepropyl in the reaction of ozone decomposition]. Zhurn. obshh. himii, 2006, vol. 76, no. 8, pp. 1320-1325 (in Russian).

Rakitskaya T.L., Truba A.S., Bandurko A.Ju. Novye metody sinteza immobilizovannyh na razlichnyh nositeljah kompleksov Cu(II), Co(II) i Mn(II) s osnovanijami Shiffa [New methods for synthesis of complexes of Cu(II), Co(II), and Mn(II) with Schiff bases immobilized on various supportd]. Visn. Odes'k. nac. un-tu. Himija, 2006, vol. 11, no. 1, pp. 14-25 (in Russian).

Rakitskaya T.L., Truba A.S., Raskola L.A., Ennan A.A. Nizkotemperaturnye Cu-soderzhashhie katalizatory razlozhenija ozona [Low-temperature Cu containing catalysts for ozone decomposition]. Visn. Odes'k. nac. un-tu. Himija, 2008, vol. 13, no. 2, pp. 73-92 (in Russian).

Rakyts’ka T., Ennan A., Raskola L., Truba A., Kytajs’ka V. Nyz’kotemperaturnyj rozklad ozonu zakriplenymyna klynoptyloliti acydokompleksamy Cu(II) [The low-temperature ozone decomposition with clinoptilolite anchored Cu(II) acido complexes]. Visn. L'viv. un-tu. Ser. him., 2010, no. 51. pp. 135-140 (in Ukrainian).

Rakitskaya T.L., Truba A.S., Golub A.A., Radchenko E.A. Razlozhenie ozona immobilizovannymi na ajerosile oksial’diminami [Ozone decomposition with aerosil immobilized oxyaldimines]. Visn. Odes'k. nac. un-tu. Himija, 2010, vol. 15, no. 2, pp. 15-22 (in Russian).

Rakitskaya T.L., Truba A.S., Golub A.A., Kiose T.A., Radchenko E.A. Vlijanie sostava i stroenija kompleksov kobal'ta(II) s oksial'diminopropilajerosilami na ih kataliticheskuju aktivnost' v reakcii razlozhenija ozona [The influence of the composition and structure of complexes of cobalt(II) with oxyaldiminepropyl aerosils on their catalytic activity in the reaction of ozone decomposition]. Teoret. i jeksperim. himija, 2011, vol. 47, no. 5, pp. 321-326 (in Russian).

Rakitskaya T.L., Raskola L.A., Truba A.S., Kiose T.A., Reznik L.I. Kataliticheskoe razlozhenie ozona zakreplennymi na prirodnom klinoptilolite acidokompleksami kobal'ta(ІІ) [The catalytic ozone decomposition with natural clinoptilolite anchored cobalt(II) acido complexes]. Voprosy khimii i khimicheskoi technologii, 2011, no. 2, pp. 118-123 (in Russian).

Rakyts’ka T.L., Red'ko T.D. Okisnennja fosfіnu perhloratnimi kompleksami mіdі(ІІ), nanesenimi na aktivovane vugіllja [The phosphine oxidation with activated carbon supported copper(II) perchlorate complexes]. Visn. Odes'k. nac. un-tu. Himija, 2002, vol. 7, no. 7-8, pp. 138-145 (in Ukrainian).

Rakitskaya T.L., Ennan A.A.. Ecological catalysis: theoretical and practical aspects. EERO USAID Symp. Ecolog. Chem.: Abstr., Moldova, Chişinău, 1995. p. 7.

Rakitskaya T.L., Pshenica M.P., Koroznikova L.I. Reakcionnaja sposobnost' nanesennyh i rastvorennyh kompleksov selena(IV) pri vosstanovlenii fosfinom [The reactivity of supported and dissolved selenium(IV) complexes]. Izv. vyssh. ucheb. zaved. Himija i him. tehnologija,, 1986, vol. 29, no. 8, pp. 21-26 (in Russian).

Rakitskaya T.L., Kostjukova I.S., Red'ko T.D. Nekotorye osobennosti okislenija fosfina hloridnymi kompleksami zheleza(III) [Some features of phosphine oxidation with iron(III) chloride complexes]. «Kataliticheskie reakcii v zhidkoj faze»: tez. dokl. 7 Vsesojuz. Simpoziuma [“Catalytic Reactions in Liquid Phase”: brief outline reports of 7th All-Union Symp.]. Kazahstan, Alma-Ata, 1988, p. 71 (in Russian).

Rakitskaja T.L., Kiose T.A., Volkova V.Ja., Zaharija A.N. Adsorbcija medi(II) prirodnym i kislotno-modificirovannym ceolitom – bazal'tovym tufom [Copper(II) adsorption by natural and acid-modified zeolite, basalt tuff].Voprosy khimii i khimicheskoi technologii, 2007, no. 6, pp. 183-186 (in Russian).

Rakitskaya T.L., Reznik L.I., Kiose T.A., Ennan A.A., Hitrich V.F. Rentgenofazovoe issledovanie zakreplennogo na bazal'tovom tufe Pd(II)-Cu(II)-katalizatora [The X-ray phase investigation of a basalt tuff anchored Pd(II)-Cu(II) catalyst]. Visn. Odes'k. nac. un-tu. Himija, 2007, vol. 12, no. 2, pp. 99-110 (in Russian).

Rakitskaya T.L., Vasilechko V.O., Kiose T.A., Grishhuk G.V., Volkova V.Ja. Adsorbcionno-desorbcionnye svojstva bazal'tovyh tufov i kataliticheskaja aktivnost' acidokompleksov palladija(ІІ) i medi(ІІ) v reakcii okislenija oksida ugleroda(ІІ) kislorodom [Adsorption-desorption properties of basalt tuffs and catalytic activity of palladium(II) and copper(II) acido complexes in the reaction of carbon(II) oxide oxidation with oxygen]. Zhurn. priklad. himii, 2010, vol. 83, no. 7, pp. 1079‑1084 (in Russian).

Rakitskaya T.L., Raskola L.A., Kiose T.A., Zaharija A.N., Kitajskaja V.V. Adsorbcija ionov 3d-metallov prirodnym i kislotno-modificirovannym klinoptilolitom [Adsorption of ions of 3d metals by natural and acid-modified clinoptilolite]. Visn. Odes'k. nac. un-tu. Himija, 2010, vol. 15, no. 3, pp. 85-91 (in Russian).

Rakitskaya T.L., Truba A.S., Davtjan A.S., Berezina L.V. Kataliticheskaja aktivnost' zakreplennyh na bazal'tovom tufe hlorokompleksov Cu(II), Co(II)i Mn(II) [The catalytic activity of basalt tuff anchored chloride complexes of Cu(II), Co(II), and Mn(II)]. Visn. Odes'k. nac. un-tu. Himija, 2010, vol. 15, no. 1-2, pp. 10-16 (in Russian).

Rakyts’ka T.L., Kiose T.O., Kamenjeva O.V., Myhajlova O.V. Adsorbcijni vlastyvosti pryrodnyh sorbentiv vidnosno dioksydu sirky [Adsorption properties of natural sorbents with respect to sulfur dioxide]. Visn. Odes'k. nac. un-tu. Himija, 2011, vol. 16, no. 14, pp. 91-94 (in Ukrainian).

Rakitskaya T.L., Dlubovskij R.M., Kiose T.A., Truba A.S., Oleksenko L.P., Volkova V.Ja. Adsorbcija parov vody prirodnym i himicheski modificirovannym bazal'tovym tufom [Water vapor adsorption by natural and chemically modified basalt tuff]. Himija, fizyka ta tehnologija poverhni, 2011, vol. 2, no. 1, pp.. 76-80 (in Russian).

Lloyd W.G., Rowe D.R. Palladium compositions suitable as oxidation catalysts. Patent UK, no. 1438557, 1976. 95. Dorfman Ja.A. Zhidkofaznyj kataliz (orbital'noe modelirovanie) [Liquid-Phase Catalysis (Orbital Modeling)]. Nauka KazSSR, Alma-Ata, 1981. 364 p. (in Russian).

Ennan A.A., Rakitskaya T.L., Abramova N.N., Obosnovanie vybora SIZOD dlja rabotnikov fosfornoj promyshlennosti [The foundation of a choice of the proper individual respiratory protective equipment for phosphorous industry workers]. «Sredstva individual'noj zashhity rabotajushhih»: Mater. nauch.-tehn. konf. [“Individual protective equipment for workers”: Mater. acad, research conf.]. Rossija, Sankt Peterburg, 1991, pp. 45-46 (in Russian).

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2015-06-17

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Rakitskaya, T. L. (2015). ТЕОРЕТИЧНІ ОСНОВИ РОЗРОБКИ НАНЕСЕНИХ МЕТАЛОКОМПЛЕКСНИХ КАТАЛІЗАТОРІВ. Вісник Одеського національного університету. Хімія, 20(1(53), 6–35. https://doi.org/10.18524/2304-0947.2015.1(53).44542

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