DOI: https://doi.org/10.18524/2304-0947.2018.2(66).132035

ЗАКРІПЛЕНІ НА ПРИРОДНОМУ КЛИНОПТИЛОЛІТІ ХЛОРИДИ 3d-МЕТАЛІВ У РЕАКЦІЇ НИЗЬКОТЕМПЕРАТУРНОГО ОКИСНЕННЯ ДІОКСИДУ СІРКИ КИСНЕМ ПОВІТРЯ

T. L. Rakitskaya, Т. A. Kiose, L. A. Raskola, K. O. Golubchik, A. B. Shulga, А. P. Nazar, A.A. Stoyan

Анотація


Вивчена кінетика окиснення діоксиду сірки в присутності закріплених на природному клиноптилоліті хлоридів 3d‑металів. Показано, що зразки проявляють різний час захисної дії та час досягнення напівперетворення SO2, тривалість яких залежить від природи та вмісту МСl2 (М = Cu2+, Co2+, Mn2+, Cd2+). Встановлено, що найкращі захисні кінетичні та стехіометричні параметри реакції окиснення діоксиду сірки спостерігаються в разі композиції CuCl2/П‑Кл.

Ключові слова


природний клиноптилоліт; закріплені хлориди 3d‑металів; діоксид сірки; окиснення; кисень повітря

Повний текст:

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Посилання


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Пристатейна бібліографія ГОСТ


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